A growing interest in thermoelectric materials — which convert waste heat to electricity — and pressure to improve heat transfer from increasingly powerful microelectronic devices have led to improved theoretical and experimental understanding of how heat is transported through nano-meter-scale materials.
Recent research has focused on the possibility of using interference effects in phonon waves to control heat transport in materials. Wave interference is already used to control electronic, photonic and acoustic devices. If a similar approach can be used in thermal transport, that could facilitate development of more efficient thermoelectric and nano-electronic devices, improved thermal barrier coatings, and new materials with ultralow thermal conductivity.
Researchers are excited on recent developments and predicts future advances in phonon wave interference and thermal band gap materials.
Researchers are trying to make heat behave as a wave and have interference while controlling how far it moves. It is basically possible to control all the properties behind heat transport. This would be a completely new way to understand and manipulate heat.
In the classic definition, heat consists of vibrations in the atomic lattices of materials. The more vibrations in a material’s structure, the hotter the material. And in the same way that white light is actually composed of many different colours of light, these thermal phonons are made up of many different frequencies — each carrying varying amounts of heat.
Recent developments have shown that thermal phonons can interfere with their own reflections. The observation suggests that thermal phonons must exist as waves similar to electronic, photonic or acoustic waves. This interference could potentially be used to modify the velocity of phonons and the density of states, creating energy band gaps that are forbidden for phonon waves. Utilization of similar band gaps in optical and electronic materials has been key to developing a wide range of useful devices.
Until now, heat transport in nanostructured materials has largely been controlled by introduction of atomic-scale impurities, interfaces, surfaces and nanoparticles that reduce heat flow by scattering the phonons diffusely. Controlling wave effects could facilitate new approaches involving the specular reflection and transmission of thermal vibrations at interfaces.
Considering the remarkable success achieved when using electronic, photonic and phononic wave interference to manipulate electrons, light and sound waves, it is certainly valuable to extend these theories to thermal vibrations, thereby creating a fundamentally new approach for manipulating heat flow.
Thermoelectric materials capture waste heat from sources such as automobile exhausts or industrial processes to produce electricity. Improving these materials will require further reducing thermal conductivity to improve their efficiency.
On the other hand, microelectronics designers want to increase thermal conductivity to transfer heat away from powerful and tiny devices. Developers of fuel cells and other conversion devices also need to improve the control of heat.
These new wave phenomena can be used to create materials with low thermal conductivity. The task involve here is thermal transport, and to interest others into the field. Ultimately, researchers will use this new information about heat transport to design better materials.
The search for thermal phononic wave materials will focus on semiconductors much like those used in microelectronics. But while the silicon used in microelectronics had a natural bandgap, scientists had to create a band gap in photonics and acoustic materials, and the same will be true for thermal materials. Likely materials include silicon-germanium, gallium and aluminum arsenide and certain oxide superlattices.
Researchers have for many years focused on how far heat may be transported in materials. For the future, research will address the velocity of that transport, and how much heat is moved in the process,
The result can be predicted by comparing heat transport to a more familiar issue — human transportation. If you want to move a lot of people, you need a bus that will carry a lot of people. You also want a vehicle that can move quickly because if you move faster, you can carry more people farther in less time.
The next few years should bring about significant clarification concerning the role of interference and bandgaps in thermal materials. That will allow continued progress in the materials needed for thermal control. It’s now a very cool thing to understand heat.